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( 2 )一定比例的合成气在装有催化剂的反应器中反应 12 小时。体系中甲醇的产率和催化剂的催化活性与温度的关系如图 1 所示。 1 温度为 490K 时,图中 P 点 _______________ (填 “ 是 ” 或 “ 不是 ” )处于平衡状态。在 490K 之前,甲醇产率升高的原因可能是 _____________ ; 490K 之后,甲醇产率下降的原因是 _______________ 。 图 1 图 2 2 提高甲醇产率,应采取的措施是 _______________ 。 A .增大压强 B .升高温度 C .选择合适催化剂 D .加入大量催化剂 ( 3 )图 2 为一定比例的 CO 2 /H 2 、 CO/H 2 、 CO/CO 2 /H 2 条件下合成甲醇生成速率与温度的关系。 1 当温度为 490K 时,根据曲线 a 、 c ,判断合成甲醇的反应机理是 _______________ (填 “ I ” 或 “ II ” ) 。 I . II 2 490K 时,曲线 a 与曲线 b 相比, CO 的存在使甲醇的生成速率增大,从热力学与动力学角度, 并结合反应 i 、 ii 分析原因 _______________ 。
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