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资料显示:镁与饱和碳酸氢钠溶液反应产生大量气体和白色不溶物。某同学设计了如下实验方案并验证产物、探究反应原理。 (1)提出假设 实验I:用砂纸擦去镁条表面氧化膜,将其放入适量滴有酚酞的饱和碳酸氢钠溶液的试管中,迅速反应,产生大量气泡和白色不溶物,溶液由浅红变红。 该同学对反应中产生的白色不溶物做出如下猜测: 猜测1:白色不溶物可能为 。 猜测2:白色不溶物可能为MgCO 3 。 猜测3:白色不溶物可能是碱式碳酸镁[xMgCO 3 ·yMg(OH) 2 ]。 (2)设计定性实验确定产物并验证猜测: 实验序号 实验 实验现象 结论 实验Ⅱ 将实验I中收集到的气体点燃 能安静燃烧、产生淡蓝色火焰 气体成分为 ___ ? ___ 实验Ⅲ 取实验I中的白色不溶物,洗涤,加入足量 ? ? 白色不溶物可能含有MgCO 3 实验Ⅳ 取实验I中的澄清液,中加入少量CaCl 2 稀溶液 产生白色沉淀 溶液中存在 ④ 离子 (3)为进一步确定实验I的产物,设计定量实验方案,如图所示: 称取实验Ⅰ中所得干燥、纯净的白色不溶物22.6 g,充分加热至不再产生气体为止,并使分解产生的气体全部进入装置A和B中。实验前后装置A增重1.8 g,装置B增重8.8 g,试确定白色不溶物的化学式 。 (4)请结合化学用语和化学平衡移动原理解释Mg和NaHCO 3 溶液反应产生大量气泡的原因_________。
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A.
正确
B.
错误
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A.
Yes, it's
B.
No, it not
C.
No, it is
D.
Yes, it is
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